6533b836fe1ef96bd12a0ad5

RESEARCH PRODUCT

Cobalt hexacyanoferrate–poly(methyl methacrylate) composite: Synthesis and characterization

Silvia ZamponiMaria Luisa SaladinoMario BerrettoniEugenio CaponettiMarco GiorgettiRoberto MatassaAntonio Zanotto

subject

Materials scienceTHERMOCHROMIC NANOPARTICLEStransmission electron microscopy (tem)Composite numberNanoparticleInfrared spectroscopytransmission electron microscopy (tem); thermochromic nanoparticles; cobalt hexacyanoferrate; nano-composites; pmma; electron microscopy; polymers; nanocompositeNANOCOMPOSITECOBALT HEXACYANOFERRATEchemistry.chemical_compoundDynamic light scatteringPolymer chemistryGeneral Materials ScienceMethyl methacrylatepolymersSettore CHIM/02 - Chimica Fisicachemistry.chemical_classificationNanocompositeelectron microscopyPolymerCobalt hexacyanoferrate PMMA Nanocomposite Thermochromic nanoparticlesCondensed Matter PhysicsPMMAPoly(methyl methacrylate)chemistryChemical engineeringvisual_artvisual_art.visual_art_mediumnano-composites

description

Abstract The preparation of cobalt hexacyanoferrate nanoparticles–poly(methyl methacrylate) (CoHCF–PMMA) composites are described together with their characterization and thermochromic properties. CoHCF nanoparticles – investigated by dynamic light scattering – were prepared by optimizing solvent composition and temperature to obtain nanoparticles with a reduced degree of aggregation. The nanoparticles were embedded in a PMMA matrix to obtain a transparent coloured composite which was studied by transmission electron microscopy. The nanoparticle chromic features, enhanced by their reduced sizes, were investigated by UV–vis and FT-IR spectroscopy.

https://doi.org/10.1016/j.matchemphys.2009.10.032