6533b836fe1ef96bd12a0b17

RESEARCH PRODUCT

Unusual crystallization kinetics in a hard sphere colloid-polymer mixture.

subject

description

We investigated the crystallization kinetics of a hard sphere colloid-polymer mixture at conditions where about 95% of solid coexists with about 5% of fluid. From time resolved Bragg and small angle light scattering, we find that the crystallite size increases with a power law of exponent alpha approximately 1/3 during both the conversion and the coarsening stage. This observation points to a single conserved order parameter for both stages and cannot be explained if the mixture is regarded as an effective one-component system. We alternatively suggest that--based on local geometric demixing--the polymer density takes the role of the conserved order parameter.