Physicochemical Properties of A New PEGylated Polybenzofulvene Brush for Drug Encapsulation

6533b836fe1ef96bd12a0b80

RESEARCH PRODUCT

Physicochemical Properties of A New PEGylated Polybenzofulvene Brush for Drug Encapsulation

Chiara Botta Gianluca Giorgi Mariano Licciardi Antonella Caterina Boccia Germano Giuliani Eugenio Paccagnini Vincenzo Razzano Annalisa Reale Mariangela Gentile Marco Paolino Filippo Samperi Alessandro Donati Laura Salvini Raniero Mendichi Daniele Piovani Andrea Cappelli Cristina Savoca

subject

lcsh:RS1-441 Pharmaceutical Science Affinity polymerization; Drug delivery systems; Grafting through; Nanocarrier; PEGylation; Polybenzofulvene; Spontaneous polymerization 02 engineering and technology 010402 general chemistry Polymer brush 01 natural sciences Article lcsh:Pharmacy and materia medica drug delivery systems chemistry.chemical_compound Dynamic light scattering Side chain drug delivery system chemistry.chemical_classification affinity polymerization grafting through polybenzofulvene PEGylation Polymer 021001 nanoscience & nanotechnology Macromonomer 0104 chemical sciences spontaneous polymerization Polymerization chemistry Chemical engineering PEGylation; grafting through; polybenzofulvene; nanocarrier; drug delivery systems; spontaneous polymerization; anity polymerization Drug delivery nanocarrier 0210 nano-technology Ethylene glycol

description

A new polymer brush was synthesized by spontaneous polymerization of benzofulvene macromonomer 6-MOEG-9-T-BF3k bearing a nona(ethylene glycol) side chain linked to the 3-phenylindene scaffold by means of a triazole heterocycle. The polymer structure was studied by SEC-MALS, NMR spectroscopy, and MALDI-TOF MS techniques, and the results supported the role of oligomeric initiatory species in the spontaneous polymerization of polybenzofulvene derivatives. The aggregation features of high molecular weight poly-6-MOEG-9-T-BF3k-FE were investigated by pyrene fluorescence analysis, dynamic light scattering studies, and transmission electron microscopy, which suggested a tendency towards the formation of spherical objects showing dimensions in the range of 20&ndash

year	journal	country	edition	language
2019-09-01	Pharmaceutics

https://doi.org/10.3390/pharmaceutics11090444

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