6533b836fe1ef96bd12a0d1a
RESEARCH PRODUCT
Tellurium(II)-Centered Dications from the Pseudohalide “Te(OTf)2”
Jason DuttonHeikki TuononenPaul Ragognasubject
dikationittelluurihalidittellurium halidesdicationsdescription
Te for two: Supported by pyridine- or carbene-based ligands, tellurium-centered dications are prepared in high yield and include a dicationic tellurium analogue of the recently synthesized “carbodicarbene”. The key to accessing these compounds is the isolation of a base-stabilized form of TeOTf2 (see structure), a new highly electrophilic reagent for tellurium chemistry. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2009-01-01 |