Electrochemical synthesis of coenzymes Qn by oxidation of tetramethoxy precursors

6533b836fe1ef96bd12a0f1e

RESEARCH PRODUCT

Electrochemical synthesis of coenzymes Qn by oxidation of tetramethoxy precursors

Maria Antonietta Sabatino Giuseppe Filardo Alessandro Galia Onofrio Scialdone

subject

Anodic oxidation Ubiquinones Settore ING-IND/27 - Chimica Industriale E Tecnologica Electrosynthesi Coenzymes Qn

description

The electrochemical oxidation of tetramethoxy precursors (2) to coenzymes Q (n) (1) at a carbon anode was investigated both in a bench-scale batch electrochemical reactor and in a continuous recirculation reaction system equipped with a parallel-plate electrochemical divided cell. High faradic efficiency (> 60%) and excellent selectivity (> 90%) in coenzymes Q (n) were obtained in CH3CN or CH3CN/CH2Cl2 + 0.15 M Bu4NBF4 under potentiostatic or amperostatic alimentation.

year	journal	country	edition	language
2009-01-01

http://hdl.handle.net/10447/58312

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