Synthesis of new soluble polybenzyls by Friedel-Crafts reactions

6533b836fe1ef96bd12a11e3

RESEARCH PRODUCT

Synthesis of new soluble polybenzyls by Friedel-Crafts reactions

Alain Dormond Denise Baudry Fabrice Dumont Fabienne Duriau-montagne

subject

chemistry.chemical_classification Thermogravimetric analysis Condensation polymer Polymers and Plastics Organic Chemistry Nuclear magnetic resonance spectroscopy chemistry.chemical_compound Differential scanning calorimetry chemistry Materials Chemistry Alkoxy group Organic chemistry Friedel–Crafts reaction Mesitylene Alkyl

description

Soluble polybenzyls were prepared by a catalytic electrophilic Friedel-Crafts type polycondensation between α,α'-dichloro-p-xylene and substituted (by an alkyl or an alkoxy side-chain) mesitylene. The influence of the length of the side-chain on the solubility of the polymer was examined. The polymers were found to be soluble in common organic solvents. Polymer characterizations were made by 13 C nuclear magnetic resonance spectroscopy (NMR), size exclusion chromatography (SEC), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and elemental analysis.

year	journal	country	edition	language
1999-03-01	Polymer International

https://doi.org/10.1002/(sici)1097-0126(199903)48:3<165::aid-pi125>3.0.co;2-y

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