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RESEARCH PRODUCT
Electrochemical Formation of 3,5-Diimido-1,2-dithiolanes by Dehydrogenative Coupling
Vincent KilianTile GieshoffValentina M. BreisingSiegfried R. WaldvogelDieter SchollmeyerAnton Kehlsubject
Electrolysis010405 organic chemistryChemistryOrganic ChemistryDisulfide bond010402 general chemistryElectrochemistry01 natural sciencesBiochemistryCombinatorial chemistry0104 chemical scienceslaw.inventionCoupling (electronics)lawMoietyPhysical and Theoretical Chemistrydescription
A synthetic approach to the cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives starting with readily available precursors including the electrochemical coupling of dithioanilides is developed. The electrochemical key step provides sustainable synthetic access in high yields, using a very simple electrolysis setup.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-10-15 | Organic Letters |