Synthesis and reactivity of P-ferrocenylalkylidenephosphanes and related iminophosphanes and diphosphenes

6533b836fe1ef96bd12a14e6

RESEARCH PRODUCT

Synthesis and reactivity of P-ferrocenylalkylidenephosphanes and related iminophosphanes and diphosphenes

Karri Airola Rudolf Pietschnig Martin Nieger Edgar Niecke

subject

Structure analysis Diphosphene Stereochemistry Organic Chemistry Diphosphenes Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Ferrocene Computational chemistry Materials Chemistry Diphosphane Reactivity (chemistry)Physical and Theoretical Chemistry

description

P-Ferrocenyl-substituted alkylidenephosphanes have been prepared and characterized spectroscopically. Their ready conversion to the corresponding acylphosphanes and 1,2-diacyldiphosphanes, as well as a new type of phosphirene synthesis are presented. The X-ray structure of the tetraferrocenyl-substituted diacyldiphosphane has been investigated. Furthermore, P-ferrocenyl iminophosphanes and their complexation behaviour are described. Diferrocenyldiphosphene, which is known to be unstable, has been stabilized by complexation; this has been confirmed by NMR-spectroscopy and X-ray structure analysis.

year	journal	country	edition	language
1997-02-01	Journal of Organometallic Chemistry

https://doi.org/10.1016/s0022-328x(96)06482-0

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