6533b837fe1ef96bd12a1e27

RESEARCH PRODUCT

Recyclable heterogeneous palladium catalysts in pure water: sustainable developments in Suzuki, Heck, Sonogashira and Tsuji-Trost reactions

Eric FouquetFrançois-xavier FelpinJean-cyrille HiersoMarc LamblinLuma Nassar-hardy

subject

Green chemistryheterogeneous palladium catalysts010405 organic chemistrywaterSonogashira couplingchemistry.chemical_elementGeneral Chemistry[CHIM.CATA]Chemical Sciences/Catalysis010402 general chemistryHeterogeneous catalysis01 natural sciences7. Clean energySuzuki reaction -Tsuji-Trost reaction0104 chemical sciencesCatalysisTsuji–Trost reaction[ CHIM.CATA ] Chemical Sciences/CatalysisHeck reactionchemistrySuzuki reactionHeck reactionOrganic chemistrySonogashira reactionComputingMilieux_MISCELLANEOUSPalladium

description

This review summarizes the progress made essentially these last ten years on heterogeneous palladium catalysis in pure water. The work covers four important palladium-catalyzed transformations for carbon-carbon bond formation: Suzuki, Heck, Sonogashira and Tsuji-Trost reactions. The discussion focuses on the efficiency and reusability of the heterogeneous catalysts as well as on the experimental conditions from a sustainable chemistry point of view. The review is introduced by a discussion on mechanistic aspects inherent to heterogeneous catalysis.

10.1002/adsc.200900765https://hal.archives-ouvertes.fr/hal-00460149