6533b837fe1ef96bd12a2032
RESEARCH PRODUCT
Crystal structure of lactitol (4-O-beta-D-galactopyranosyl-D-glucitol).
I. PitkänenHeikki HeikkiläJussi ValkonenJussi Kivikoskisubject
Models MolecularLactitolHydrogen bondStereochemistryOrganic ChemistryCyclohexane conformationMolecular Sequence DataHydrogen BondingGeneral MedicineCrystal structureRing (chemistry)BiochemistryAnalytical ChemistryBond lengthchemistry.chemical_compoundCrystallographySugar AlcoholschemistryCarbohydrate SequenceX-Ray DiffractionD-glucitolCarbohydrate ConformationSoftwareMonoclinic crystal systemdescription
Abstract Lacitol, C 12 H 24 O 11 , is monoclinic, space group P 2 1 with cell dimensions a = 7.614(1), b = 10.757(1), c = 9.370(1) A, β = 108.19(1)°, and V = 729.0(1) A 3 ; Z = 2, D x = 1.57 Mg.m −3 , λ(Cu- K α ) = 1.5406 A, μ = 1.166 mm −1 , F (000) = 368, and T = 23°. The structure was solved by direct methods and refined by least-squares calculations to R = 0.048 for 1510 unique observed reflections. There are one intra- and eight inter-molecular hydrogen bonds in the structure. Bond lengths and angles accord well with the mean values of related structures. The galactopyranosyl ring has a chair conformation.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1992-01-01 | Carbohydrate research |