6533b837fe1ef96bd12a210d
RESEARCH PRODUCT
Expansion and Compression of a Helicate with Central Diol-Units as Stereocontrolling Moieties
Saskia GrüningerChristian MevissenJas S. WardKari RissanenMarkus Albrechtsubject
helicatelitiumstereochemistrykationitsupramolekulaarinen kemiamolekyylitnanotekniikkaself-assemblykompleksiyhdisteetmetallitmolecular switchdescription
The dicatechol ester ligand 2-H4 forms the compressed helicate Li4[(2)3Ti2] which upon removal of the internally bound lithium cations expands. In the compressed form, the chiral diol units control the stereochemistry of the complex which is lost upon expansion of the system. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2022-01-01 |