6533b837fe1ef96bd12a278e
RESEARCH PRODUCT
Oxidative cyclization of aldehyde thiosemicarbazones induced by potassium ferricyanide and by tris(p-bromophenyl)amino hexachloroantimoniate. A joint experimental and computational study
Paolo Lo MeoRenato NotoMichelangelo Gruttadauriasubject
chemistry.chemical_classificationTrisOxidative cyclizationOrganic ChemistryOxidative cyclization thiosemicarbazones 124-triazolesOxidative phosphorylationSettore CHIM/06 - Chimica OrganicaRing (chemistry)AldehydeMedicinal chemistrylcsh:QD241-441Potassium ferricyanidechemistry.chemical_compoundlcsh:Organic chemistrychemistryOrganic chemistrydescription
The oxidative ring closure reaction of some aryl-substituted thiosemicarbazones induced by "bona fide" one-electron abstracting agents was investigated, by means of both experimental and computational techniques. The corresponding 1,2,4-triazole derivatives were the only cyclization products observed. The occurrence of two slightly different mechanistic pathways for the reaction is discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-02-01 |