6533b837fe1ef96bd12a31fa
RESEARCH PRODUCT
Molecular Engineering To Control the Magnetic Interaction between Single-Chain Magnets Assembled in a Two-Dimensional Network
Catalina Ruiz‐pérezFrancesc LloretJorge PasánLuminita Marilena TomaWolfgang WernsdorferMiguel Julvesubject
[PHYS]Physics [physics]Condensed matter physics010405 organic chemistryChemistryRelaxation (NMR)General ChemistrySingle chain010402 general chemistry01 natural sciencesBiochemistryCatalysis0104 chemical sciencesMolecular engineeringMagnetizationCrystallographyColloid and Surface ChemistryMagnetMagnetic interactiondescription
International audience; Two two-dimensional (2D) systems having the formula [{Fe-III(dmbpy)(CN)(4)}(2)(CoL)-L-II](n) [L = pyetNO (1), tvpNO (2)] and consisting of single-chain magnets connected through organic ligands (L) have been prepared, and their magnetic properties have been investigated. The overall magnetic behavior depends on the capacity of the organic pillars to transmit long-range magnetic interactions. 1 is the first example of a 2D compound exhibiting double relaxation of the magnetization, whereas 2 behaves as a metamagnet.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-09-19 |