Selective access to either a doubly boron-doped tetrabenzopentacene or an oxadiborepin from the same precursor

6533b837fe1ef96bd12a321b

RESEARCH PRODUCT

Selective access to either a doubly boron-doped tetrabenzopentacene or an oxadiborepin from the same precursor

Marcel Bamberg Dieter Schollmeyer Michael Bolte Matthias Wagner Kai Schickedanz Luigi Menduti Julian Radtke Hans-wolfram Lerner

subject

chemistry.chemical_classification Anthracene Reaction mechanism 010405 organic chemistry chemistry.chemical_element General Chemistry Electron acceptor 010402 general chemistry 01 natural sciences 0104 chemical sciences Chemistry chemistry.chemical_compound Crystallography chemistry Intramolecular force Yield (chemistry)Pyridine Moiety Boron

description

Depending on the solvent, a brominated arylborane gave the multiple helicene B2-TBPA (pyridine) or the oxadiborepin ODBE (THF) after intramolecular Yamamoto coupling.

year	journal	country	edition	language
2019-06-24	Chemical Science

https://doi.org/10.1039/c9sc03115d

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