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RESEARCH PRODUCT
The crystallisation of copper(ii) phenylphosphonates
Uwe ReinholzFranziska EmmerlingUte KolbManuel WilkeManuel WilkeAnke KabelitzAnke KabelitzKlaus RademannTatiana GorelikAna Guilherme Buzanichsubject
Materials scienceExtended X-ray absorption fine structurechemistry.chemical_element02 engineering and technologyCrystal structure010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesCopperHydrothermal circulation0104 chemical scienceslaw.inventionInorganic ChemistryCrystallographyElectron diffractionchemistrylawCrystallizationAbsorption (chemistry)0210 nano-technologySingle crystaldescription
The crystal structures and syntheses of four different copper(II) phenylphosphonates, the monophenylphosphonates α-, β-, and γ-Cu(O3PC6H5)·H2O (α-CuPhPmH (1) β-CuPhPmH (2) and γ-CuPhPmH (3)), and the diphosphonate Cu(HO3PC6H5)2·H2O (CuPhP2mH (4)), are presented. The compounds were synthesized from solution at room temperature, at elevated temperature, under hydrothermal conditions, and mechanochemical conditions. The structures of α-CuPhPmH (1) and CuPhP2mH (4) were solved from powder X-ray diffraction data. The structure of β-CuPhPmH (2) was solved by single crystal X-ray analysis. The structures were validated by extended X-ray absorption fine structure (EXAFS) and DTA analyses. Disorder of the crystal structure was elucidated by electron diffraction. The relationship between the compounds and their reaction pathways were investigated by in situ synchrotron measurements.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-11-02 | Dalton Transactions |