6533b838fe1ef96bd12a4f28
RESEARCH PRODUCT
XAFS study of short range order in the heavily disordered MoxW1−wO3 oxides
Juris PuransPh. ParentAlexei KuzminH. Dexpertsubject
Materials scienceMetal ions in aqueous solutionShell (structure)Analytical chemistryCrystal structureCondensed Matter PhysicsElectronic Optical and Magnetic MaterialsX-ray absorption fine structuresymbols.namesakesymbolsCrystalliteElectrical and Electronic EngineeringRaman spectroscopyChemical compositionSolid solutiondescription
We have done comparative XAFS analysis on the MoK and WL 3 edges of polycrystalline Mo x W 1-x O 3 solid solutions. It was found that their structures are closely related to corner-shared WO 3 -type for x<0.9 while α-MoO 3 -type structure is present for x≥0.9. The obtained structural parameters for the first shell around metal ions allow to distinguish several structural phase transitions due to the change of composition. A set of subshells within the first shell was found, and they are in good agreement with Raman data
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1995-03-01 | Physica B: Condensed Matter |