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RESEARCH PRODUCT
[FeIILSCoIIILS]2⇔ [FeIIILSCoIIHS]2 photoinduced conversion in a cyanide-bridged heterobimetallic molecular square
Mannan SeuleimanEmilio PardoJulie MercurolHélène RousselièreMiguel JulveYanling LiRodrigue LescouëzecOlivia N. Rissetsubject
StereochemistryCyanideMetals and AlloysLight irradiationGeneral ChemistryCatalysisSquare (algebra)Surfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundCrystallographychemistryMaterials ChemistryCeramics and CompositesDiamagnetismdescription
The self-assembly of [Fe(III){B(pz)(4)}(CN)(3)](-) and [Co(II)(bik)(2)(S)(2)](2+) affords the diamagnetic cyanide-bridged [Fe(II)(LS)Co(III)(LS)](2) molecular square which is converted into the corresponding magnetic [Fe(III)(LS)Co(II)(HS)](2) species under light irradiation at relatively low temperatures.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-10-23 | Chemical Communications |