6533b838fe1ef96bd12a5281
RESEARCH PRODUCT
Separation of Enantiomers in a Monolayer of Racemic 3-Hexadecyl-oxy-propane-1,2-diol
Gerald BrezesinskiHelmuth MöhwaldRoland Rietzsubject
chemistry.chemical_compoundAqueous solutionchemistryStereochemistryPropaneGeneral Chemical EngineeringDiolMonolayerPhysical chemistryRacemic mixtureEnantiomerSurface pressureEnantiomeric excessdescription
Monolayers of a racemic mixture and of the pure S enantiomer of 3-hexadecyloxy-propane-1,2-diol have been characterized by thermodynamic measurements at the air/water interface as well as by fluorescence microscopy. The critical temperatire T c , the limiting molecular area at high pressure and the pressure π c corresponding to the observed main phase transition, derived from the isotherms, slightly depend on chiral purity
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1993-10-01 | Berichte der Bunsengesellschaft für physikalische Chemie |