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RESEARCH PRODUCT

Influence of the Substituent on Selective Photocatalytic Oxidation of Aromatic Compounds in Aqueous TiO2 Suspensions.

Elisa I. García-lópezGiovanni PalmisanoVincenzo AugugliaroVittorio LoddoLeonardo PalmisanoMaurizio AddamoTullio Caronna

subject

Settore CHIM/03 - Chimica Generale e InorganicaAqueous solutionMetals and AlloysSubstituenthot electronGeneral ChemistryGeneral MedicineMedicinal chemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundSubstituent effectchemistryPhotocatalysis; TiO2; Substituent effect; OxydationGroup (periodic table)PhotocatalystsMaterials ChemistryCeramics and CompositesPhotocatalysisTiO2Organic chemistryOxydationPhotocatalysis

description

Experimental results are reported showing that the photocatalytic oxidation of aromatic compounds containing an electron-donor group (EDG) gives rise mainly to ortho- and para-monohydroxy derivatives while in the presence of an electron-withdrawing group (EWG) all the monohydroxy derivatives are obtained.

https://doi.org/10.1002/chin.200628032