6533b839fe1ef96bd12a5910
RESEARCH PRODUCT
Alkali-metal induced C,C-bond cleavage, C,H-bond cleavage, andcyclopolimerization in 1,5-hexadienes
Klaus MüllenRainer Trinkssubject
C h bondchemistryHydridePotassiumOrganic ChemistryDrug Discoverychemistry.chemical_elementCleavage (crystal)Alkali metalPhotochemistryBiochemistryMedicinal chemistryBond cleavagedescription
Abstract Reaction of the 1,5-dienes 3,4-homotropilidene ( 3 ) and 2,5-diphenylhexa-1,5-diene ( 4 ) with alkali metals induces C,H-bond cleavage (hydride formation) and cyclopolymerization, respectively, in contrast to the C,C-bond cleavage observed in semibullvalene and barbaralane.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1988-01-01 | Tetrahedron Letters |