6533b839fe1ef96bd12a598a

RESEARCH PRODUCT

Removal of hexavalent chromium from wastewaters by bone charcoal

M. De La GuardiaM. AzziS. Dahbi

subject

inorganic chemicalsfood and beverageschemistry.chemical_elementMineralogySorptionrespiratory systemequipment and suppliesBiochemistryTannery effluentscarbohydrates (lipids)Matrix (chemical analysis)ChromiumSample volumechemistry.chemical_compoundAdsorptionchemistryvisual_artvisual_art.visual_art_mediumHexavalent chromiumCharcoalNuclear chemistry

description

The adsorption of hexavalent chromium onto bone charcoal was studied as a function of time, amount of charcoal, pH, concentration of chromium and sample volume. The cross interference with other elements was also investigated. Tests were carried out with solutions of chromium(VI) at concentrations between 5 and 25 mg · L–1. Chromium removal efficiencies higher than 90% were achieved at pH = 1 using 2 g of bone charcoal and a stirring time in the order of 30 min. Acid and alkaline pretreatments of bone charcoal did not improve the sorption capacity of bone charcoal against Cr(VI). The presence of other ions had practically no influence on the chromium removal. The presence of a matrix of tannery effluents did not reduce the removal capacity of bone charcoal for Cr(VI), but it was confirmed that only 47% of Cr(III) can be removed using these conditions.

https://doi.org/10.1007/s002160051210