Racēmisko 4-aizvietoto pirolidīn-2-ona atvasinājumu sadale uz polisaharīdu bāzes pārklātiem hirāliem sorbentiem

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RESEARCH PRODUCT

Racēmisko 4-aizvietoto pirolidīn-2-ona atvasinājumu sadale uz polisaharīdu bāzes pārklātiem hirāliem sorbentiem

subject

HIRĀLIE SORBENTI MOBILĀ FĀZE AUGSTI EFEKTĪVĀ ŠĶIDRUMU HROMATOGRĀFIJA ENANTIOMĒRU SADALĪŠANA Ķīmija

description

Darbā analizēti literatūras avoti par enantiomēru sadali, izmantojot augsti efektīvo šķidrumu hromatogrāfiju uz polisaharīdu bāzes pārklātiem hirāliem sorbentiem. Eksperimentālajā daļā tika veikta 15 hirālu 4-aizvietotu pirolidīn-2-onu atvasinājumu enantiomēru analīze uz sešiem polisaharīdu bāzes pārklātiem hirāliem sorbentiem, izmantojot dažādas mobilās fāzes. Noskaidrots, ka enatiomēru sadale ir atkarīga gan no hirālā sorbenta dabas, gan no mobilās fāzes organiskā modifikatora. Labākā sadale sasniegta uz hirāliem sorbentiem, kas veidoti uz amilozes bāzes (Lux Amylose-1 un Lux Amylose-2).

year	journal	country	edition	language
2017-01-01

https://dspace.lu.lv/dspace/handle/7/45447

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