6533b839fe1ef96bd12a6d0f

RESEARCH PRODUCT

Tris(cyclohexylammonium) cis-dichloridobis(oxalato-κ2O1,O2)stannate(IV) chloride monohydrate

Modou SarrWaly DialloAminata Diasse-sarrLaurent PlasseraudHélène Cattey

subject

CrystallographyQD901-999

description

The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octahedrally to the central SnIV atom. The cohesion of the molecular entities is ensured by the formation of N—H...O, O—H...O, O—H...Cl and N—H...Cl interactions involving cations, anions and the lattice water molecule, giving rise to a layer-like arrangement parallel to (010).

10.1107/s1600536813026901http://scripts.iucr.org/cgi-bin/paper?S1600536813026901