6533b839fe1ef96bd12a6d40

RESEARCH PRODUCT

Special Calixarenes, Synthesis and Properties

Volker BöhmerJacques Vicens

subject

Cone conformationchemistry.chemical_compoundChemistrySingle typeCalixareneMethylene bridgeCombinatorial chemistry

description

In the previous chapter the standard one step procedures for the synthesis of calixarenes from p-tert-butyl phenol and several p-alkyl phenols have been described. However, these procedures necessarily lead to calixarenes consisting of one single type of phenolic unit. This remains true even for those compounds in which all the terf-butyl groups are removed and replaced by other functional groups. The construction of more sophisticated, special calixarenes which could serve for instance as enzyme models, requires new synthetic approaches capable of producing molecules with selected functionalization.

https://doi.org/10.1007/978-94-009-2013-2_2