6533b839fe1ef96bd12a6e1c

RESEARCH PRODUCT

Complexes of organometallic compounds XXXIII. The coordination chemistry of dimethyl and diphenylthallium(III) ith tridentate ligands

Giuseppe RuisiR. CefalLorenzo Pellerito

subject

chemistry.chemical_classificationChemistryStereochemistryOrganic ChemistrySolid-stateInfrared spectroscopyBiochemistryCoordination complexInorganic ChemistryPolymer chemistryMaterials ChemistryPhysical and Theoretical ChemistrySpectroscopyGroup 2 organometallic chemistry

description

Summary Several novel complexes Na[Me 2 TIL] and Na[Ph 2 TIL] (L 2− =dianion tridentate ligands with S, N, and O donor atoms) were synthesized, and investigated by infrared spectroscopy in the solid state, and by electronic and PMR spectroscopy in solution. Suggestions for the configuration of the complex anions are advanced and the nature of species present in solution is discussed.

https://doi.org/10.1016/s0022-328x(73)80016-6