6533b839fe1ef96bd12a6e50

RESEARCH PRODUCT

Formation of Bridging Alkene and Conjugated Dialkenes Exclusively Generated from Alkynes on the [3,3‘-Co(1,2-C2B9H11)2]- Platform. The Unique Hydroboration Role of [3,3‘-Co(1,2-C2B9H11)2]-

Isabel RojoRaikko KivekäsC. ViñasReijo SillanpääF. Teixidor

subject

chemistry.chemical_classificationReaction mechanismHydroborationColloid and Surface ChemistryBridging (networking)ChemistryStereochemistryAlkeneAlkyneGeneral ChemistryConjugated systemBiochemistryCatalysis

description

The unprecedented metal-mediated transformation of an alkyne into a B,B' bridging alkene is reported. Also, the unprecedented synthesis of a conjugated dialkene derivative of [3,3'-Co(1,2-C2B9H11)2]- generated only from an alkyne, contrary to the usual case where an alkyne and an alkene are needed, is described. This has been possible through the singular capacity of a B-H to produce hydroboration.

yearjournalcountryeditionlanguage
2003-11-08Journal of the American Chemical Society
https://doi.org/10.1021/ja037279e