6533b839fe1ef96bd12a6e51

RESEARCH PRODUCT

Electrochemistry of hydrotalcite-supported bis(2-mercapto-2,2-diphenyl-ethanoate) dioxomolybdate complexes.

Elisa LlopisAntonio RiberaAntonio DoménechAntonio Cervilla

subject

HydrotalciteGeneral Chemical EngineeringInorganic chemistrychemistry.chemical_elementBuffer solutionSodium perchlorateElectrochemistryRedoxAnalytical Chemistrychemistry.chemical_compoundchemistryMolybdenumPolymer chemistryElectrochemistryCarboxylateCyclic voltammetry

description

The redox properties of the hydrotalcite-intercalated bis(2-mercapto-2,2-diphenyl-ethanoate) dioxomolybdate(VI) complex are investigated by cyclic voltammetry by using modified carbon paste electrodes and clay-modified electrodes. The electrochemical data provide evidence that boundary-associated species involving the VI, V and IV oxidation states of molybdenum are responsible for the electroactivity.

yearjournalcountryeditionlanguage
1998-10-01Journal of Electroanalytical Chemistry
https://doi.org/10.1016/s0022-0728(98)00231-9