6533b83afe1ef96bd12a6f43
RESEARCH PRODUCT
A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification
Emmanuel LerayerNadine PirioJulien RogerPatrice RenautDominique LucasCharles H. DevillersHélène CatteyJean-cyrille HiersoJean-cyrille Hiersosubject
catalytic applicationsPlanar chirality010402 general chemistryElectrochemistrycarbon-dioxide01 natural sciences[ CHIM ] Chemical SciencesCatalysisMaterials ChemistryOrganic chemistry[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryfree hydrogen activationaryl bromidesAlkylchemistry.chemical_classificationcomplexes010405 organic chemistryChemistryligandsdirect arylationMetals and AlloysGeneral ChemistrypalladiumCombinatorial chemistry0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialsfrustrated lewis pairsCeramics and Compositescoordination chemistrydescription
International audience; A general synthesis of highly functionalized ferrocenes, which include (P,B)- and (N,B)-ambiphiles, has been developed at a multigram scale. Diastereoselective stepwise modification of di-tert-butylated ferrocenes included the unprecedented separation of electroactive species. Bulky alkyl groups on ferrocenes ensure planar chirality of ambiphiles and enforce closer proximity of antagonist Lewis functions.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-06-04 |