6533b83afe1ef96bd12a6ff4
RESEARCH PRODUCT
Redox switching of the antiferromagnetic coupling in permethylated dicopper(ii) paracyclophanes
María CastellanoEmilio PardoRafael Ruiz-garcíaMiguel JulveFrancesc LloretJorge PasánCatalina Ruiz‐pérezJesús Ferrando-soriaYangling LiJoan CanoYves JournauxLaura Cañadillas-delgadosubject
ChemistryMetals and AlloysGeneral ChemistryPhotochemistryRedoxCatalysisAntiferromagnetic couplingSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyMaterials ChemistryCeramics and CompositesAntiparallel (electronics)description
A unique magnetic electroswitching behavior has been observed in an oxamato-based permethylated dicopper(II) paracyclophane; upon reversible one-electron oxidation of the double tetramethyl-substituted p-phenylenediamidate bridging skeleton, the spin alignment of the two Cu(II) ions (S(Cu) = ½) changes from antiparallel (OFF) to parallel (ON) in the resulting dicopper(II) π-radical cation species.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-07-17 | Chemical Communications |