6533b83afe1ef96bd12a79ab

RESEARCH PRODUCT

Heterometallic 3d−4f Polyoxometalate Derived from the Weakley-Type Dimeric Structure

Santiago ReinosoJosé Ramón Galán-mascarós

subject

Inorganic ChemistryCrystallographyChemistryPolyoxometalateCluster (physics)MoietyPhysical and Theoretical ChemistryType (model theory)Combinatorial chemistry

description

Polyanion [{Ce(H(2)O)(2)}(2)Mn(2)(B-alpha-GeW(9)O(34))(2)](8-) (1) constitutes the first example of a heterometallic 3d-4f cluster related to the Weakley-type dimeric structure, and it contains an unprecedented Ce(III)(2)Mn(III)(2)O(20) rhomblike moiety displaying dominant Ce(III)-Mn(III) ferromagnetic interactions.

https://doi.org/10.1021/ic902217g