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RESEARCH PRODUCT
Vibrational dephasing of νs (OH) in 2,4-dichlorophenol
Jerzy P. HawranekMałgorzata A. Brodasubject
InfraredPolarity (physics)DephasingOrganic ChemistryRelaxation (NMR)Analytical chemistry24-DichlorophenolAnalytical ChemistryInorganic ChemistrySolventchemistry.chemical_compoundCorrelation functionchemistrySolvent polaritySpectroscopydescription
Abstract A quantitative analysis of the infrared bandshape of ν s (OH) in intramolecularly hydrogen-bonded 2,4-dichlorophenol in a series of solvents is presented. A distinct dependence of bandshape indices and relaxation parameters on the polarity of solvent has been found. The band shifts to lower wavenumbers, broadens and becomes more intense with increasing solvent polarity; correspondingly, the correlation function decays faster and the correlation time diminishes. The results are compared with those for previously studied systems. Factors influencing the bandshape are discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1990-03-01 | Journal of Molecular Structure |