Application of 61Ni Mössbauer spectroscopy to chemical problems

6533b850fe1ef96bd12a85ca

RESEARCH PRODUCT

Application of 61Ni Mössbauer spectroscopy to chemical problems

Peter C. Schmidt B. Hannebauer D. Sellmann K. Lutar Philipp Gütlich B. ŽEmva Rüdiger Kniep N. Jansen D. Häußinger D. Walcher

subject

Hydrogenase Materials science Nuclear magnetic resonance Chemical bond Mössbauer spectroscopy General Physics and Astronomy Physical chemistry Mossbauer spectra Electronic band structure Microtron Helium temperature

description

Using the possibility to produce 61Co sources at the MAinz MIcrotron, 61Ni Mossbauer spectroscopy was applied to different kinds of chemical problems. Measurements of isomer shifts and V zz values in some common compounds and compounds with unusual chemical bonding for comparison with band structure calculations, measurement of 61Ni Mossbauer parameters in model compounds for hydrogenase and dehydrogenase with an active [NiS4] centre, and study of novel binary NiF3 compounds at helium temperature are presented.

year	journal	country	edition	language
1996-02-01	Il Nuovo Cimento D

https://doi.org/10.1007/bf02458896

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