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RESEARCH PRODUCT
Perfluoro-1,1′-biphenyl and perfluoronaphthalene and their derivatives as π-acceptors for anions
Markus AlbrechtArto ValkonenArto ValkonenKari RissanenHai Yisubject
Diffractionchemistry.chemical_classificationBiphenylanion-pi interactionsSolid-stateSalt (chemistry)General ChemistryFluorine-19 NMRCatalysisIonCrystallographychemistry.chemical_compoundchemistryMaterials ChemistryOrganic chemistryta116Single crystalNaphthalenedescription
Addition of anions to perfluorinated 1,1′-biphenyl 1 or naphthalene 2 results in a shift of the 19F NMR signals. However, any specific interaction cannot be assigned to this effect. In order to study the interaction in more detail, the salt derivatives 3 and 4 were prepared and studied by single crystal X-ray diffraction revealing weak anion–π interactions in the solid state.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-01-01 | New Journal of Chemistry |