6533b851fe1ef96bd12a9712

RESEARCH PRODUCT

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subject

Materials scienceGeneral Physics and AstronomyThermodynamicsCharge number02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences0104 chemical sciencesMagnetic fieldElectrophoresisEntropy (classical thermodynamics)NanofluidSeebeck coefficientThermoelectric effectPolar0210 nano-technology

description

An analytical model describing the thermoelectric potential production in magnetic nanofluids (dispersions of magnetic and charged colloidal particles in liquid media) is presented. The two major entropy sources, the thermogalvanic and thermodiffusion processes are considered. The thermodiffusion term is described in terms of three physical parameters; the diffusion coefficient, the Eastman entropy of transfer and the electrophoretic charge number of colloidal particles, which all depend on the particle concentration and the applied magnetic field strength and direction. The results are combined with well-known formulation of thermoelectric potential in thermogalvanic cells and compared to the recent observation of Seebeck coefficient enhancement/diminution in magnetic nanofluids in polar media.