6533b851fe1ef96bd12a991e

RESEARCH PRODUCT

The [1,2,3]triazolo[1,5-a]pyridine ring: a sensitive sensor for the electronic profile of phosphorus substituents.

Belén AbarcaFrançoise ColobertFrédéric R. LerouxRafael Ballesteros-garridoLaurence Bonnafoux

subject

Inorganic ChemistryCrystallographychemistry.chemical_compoundchemistryStereochemistryPhosphorus atomPyridine

description

The unique nature of the [1,2,3]triazolo[1,5-a]pyridine reveals without any external perturbation the electronic contribution of various substituents to the phosphorus atom in phosphines, based on the equilibrium of two possible ring-chain isomers.

10.1039/b906034khttps://pubmed.ncbi.nlm.nih.gov/19562163