6533b851fe1ef96bd12aa0ef
RESEARCH PRODUCT
Bis(2-methylbenzimidazole-κN1)copper(I) dichlorocuprate(I)
Evgeny GoreshnikDieter SchollmeyerMarian Mys'kivsubject
010405 organic chemistryCoordination numberInorganic chemistrychemistry.chemical_elementGeneral Chemistry010402 general chemistryCondensed Matter PhysicsElectrochemistry01 natural sciencesCopper0104 chemical sciences3. Good healthIonMetalchemistry.chemical_compoundCrystallographychemistryvisual_artvisual_art.visual_art_mediumImidazoleGeneral Materials ScienceCuprateIonic compounddescription
By using alternating-current electrochemical synthesis, crystals of the copper(I) ionic compound composed of [Cu(C8H8N2)2]+ and [CuCl2]− ions have been obtained and structurally investigated. Both crystallographically independent Cu atoms lie on centres of inversion and exhibit the less-common coordination number 2. A linear arrangement of the metal atoms includes two N atoms of the different organic moieties in the [Cu(2-methylbenzimidazole)2]+ cation and two Cl atoms in the case of the inorganic anion.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-02-07 | Acta Crystallographica Section E Structure Reports Online |