Heptacoordinated MnIIin oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)6][Mn(CH3OH)MIII(ox)3]2(MIII= Cr, Rh; ox = oxalate dianion; L = H2O, CH3OH)

6533b851fe1ef96bd12aa1a4

RESEARCH PRODUCT

Heptacoordinated MnIIin oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)6][Mn(CH3OH)MIII(ox)3]2(MIII= Cr, Rh; ox = oxalate dianion; L = H2O, CH3OH)

Carlos Marti-gastaldo José Ramón Galán-mascarós Ana M. Victoria Martínez Eugenio Coronado

subject

Inorganic Chemistry chemistry.chemical_compound Crystallography Materials science Octahedron chemistry Magnet Metal ions in aqueous solution Nanotechnology Bimetallic strip Oxalate Divalent metal

description

Oxalate-based magnets have been known with several different crystallographic structures, from 1D to 3D, but with all of them based in metal ions with octahedral coordination. In this article we report a new bidimensional oxalate-bridged bimetallic magnet where the divalent metal appears heptacoordinated, which has strong effects in the structure and properties of this materials.

year	journal	country	edition	language
2006-01-01	Dalton Trans.

https://doi.org/10.1039/b603504c

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