6533b852fe1ef96bd12aac6e

RESEARCH PRODUCT

Halogen-bonded solvates of tetrahaloethynyl cavitands

Mario CetinaMario CetinaLotta TurunenFangfang PanKari RissanenJohn F. TrantRobin H. A. RasNgong Kodiah BeyehNgong Kodiah Beyeh

subject

Chloroformta114010405 organic chemistryGeneral ChemistryResorcinarene010402 general chemistryCondensed Matter Physicshalogen bond ; cavitands ; resorcinarenes ; host-guest complexes01 natural sciencessupramolecular chemistrycavitands0104 chemical scienceschemistry.chemical_compoundChemistrychemistrysolvatessupramolekyylikemiaHalogenPolymer chemistryAcetoneOrganic chemistryGeneral Materials ScienceAcetonitrileta116Biochemistry Biophysics and Structural Biology

description

The formation and structures of halogen-bonded solvates of three different tetrahaloethynyl cavitands with acetone, chloroform, acetonitrile, DMF and DMSO were prepared and investigated. The inclusion and host–guest behaviour of the resorcinarene cavitands was found to be highly dependent on the flexibility of the ethylene-bridging unit.

10.1039/c7ce01118khttps://scholar.uwindsor.ca/context/chemistrybiochemistrypub/article/1207/viewcontent/19_XB_Cavi_Solv_ms_final_170614.pdf