6533b852fe1ef96bd12aadd6
RESEARCH PRODUCT
High-temperature spin crossover in a mononuclear six-coordinate cobalt(II) complex.
Joanna Palion-gazdaEmilio PardoThais GranchaBarbara MachuraMiguel JulveFrancesc LloretAnna ŚWitlicka-olszewskasubject
Inorganic ChemistryNuclear magnetic resonancechemistrySpin crossoverPhase (matter)Analytical chemistrychemistry.chemical_elementCondensed Matter::Strongly Correlated ElectronsPhysical and Theoretical ChemistrySpin (physics)Cobaltdescription
The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-09-09 | Inorganic chemistry |