6533b852fe1ef96bd12ab637

RESEARCH PRODUCT

INFLUENCE OF THE CHEMICAL POTENTIAL ON THE CARRIER EFFECTIVE MASS IN THE THERMOELECTRIC SOLID SOLUTION Cu2Zn1-xFexGeSe4

G. Jeffrey SnyderWolfgang G. ZeierWolfgang G. ZeierWolfgang TremelTristan DayEugen Schechtel

subject

Effective mass (solid-state physics)Materials scienceCondensed matter physicsThermoelectric effectAnalytical chemistryValence bandGeneral Materials ScienceThermoelectric materialsSolid solution

description

In this paper, we describe the synthesis and characterization of the solid solution Cu 2 Zn 1-x Fe x GeSe 4. Electronic transport data have been analyzed using a single parabolic band model and have been compared to Cu 2+x Zn 1-x GeSe 4. The effective mass of these undoped, intrinsically hole conducting materials increases linearly with increasing carrier concentration, showing a non-parabolic transport behavior within the valence band.

https://doi.org/10.1142/s1793604713400109