Dioxouranium(VI) hydrolysis at 75 and 100°C in 3.6 molkg-1 LiClO4

6533b852fe1ef96bd12abbf7

RESEARCH PRODUCT

Dioxouranium(VI) hydrolysis at 75 and 100°C in 3.6 molkg-1 LiClO4

Diana Amorello Vincenzo Gambino Vincenzo Romano Roberto Zingales

subject

Acid-base titrations check of equilibrium conditions hydrolysis in hot LiClO4 aqueous medium.Settore CHIM/01 - Chimica Analitica

description

This work concerns the acidic properties of uranyl ion UO22+ at 75 and 100 °C in 3.6 molal (molkg-1 solvent) LiClO4 aqueous medium. The investigation was carried out by a coulometric-potentiometric technique. Direct and reverse acid base titrations were carried out in order to check the achievement of actual equilibrium conditions. Moreover, in order to reveal oversaturation conditions, a further check was carried out on clean saturated hydrolyzed solutions.

year	journal	country	edition	language
2008-01-01

10.1007/s10953-008-9266-2 http://hdl.handle.net/10447/35113

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