6533b853fe1ef96bd12ac986

RESEARCH PRODUCT

Surfactant Association: Recent Theoretical and Experimental Developments

Philip C. ShanksP. S. GoyalKrishnan ChariS. SánchezKyoko WatanabeC. J. JohnyA. D. NikolovA. D. NikolovCamillo La MesaLui LaneLui LaneM. CostasVipendra TyagiA. N. MaitraD. BalasubramanianE. PramauroLi YongJ. SancenónAnil B. ZadeP. MariscalIshrat JahanPaul Joseph Tracy MisselV. P. MehtaP. A. PincusD. RouxP. A. KralchevskyP. A. KralchevskyRonald D. NeumanH. C. DominguezA. S. TourkyJ. StrnadA. RobledoH.-h. KohlerS. BhattacharyaD. A. TomaliaD. A. TomaliaD. A. TomaliaV. K. KelkarFang MingmingB. A. MoyerTon WeideD. O. ShahKunio MimuraL. C. HedaJ. M. DouillardJ. TexterB. A. DasannacharyaM. TerenziC. ManoharB. K. MishraB. K. MishraP. AshburnerM. J. StébéDaniel J. O’learyXia JidingXia JidingF. C. MackintoshFrank A. L. AnetM. K. PackmanGiuseppe Antonio RanieriYu XiafeiD. BlankschteinI. A. El-sabbaghKazuyuki TsuboneE. BurattiniJaques RoncinJaques RoncinZukang ZhouG. CerichelliC. A. LittauC. A. BuntonM. De La GuardiaA. BlaskoA. RaudinoR. ZanaM. PathakMuzayan JahanP. D’angeloR. O. CastilloZhi-jian YuJean FaureJean FaureE. StaudeJ. L. CarriónJ. S. HuangA. R. LaceyE. OrthgießB. DobiášJ. GraciaKailash N. MunshiAshok N. BhaskarwarAnjani J. VarmaH. N. SinghA. K. JainM. PrivatW. Binana-limbeléM. HasanS. A. SafranM. M. El-fassK. R. WormuthElias I. FransesG. BrozeYang PeizengF. R. HorchWilliam Binana-limbeleD. C. MckenzieI. B. IvanovI. B. IvanovN. J. TurroN. J. TurroN. J. TurroR. BacalogluS. QutubuddinR. RennasG. J. LumettaG. Martinez-meklerJ. C. RaveyY. M. YangWilliam C. LenhartTong WeideF. MalejkaJohn C. ShelleyC. VareaSavita A. VaidyaRobert PansuRobert PansuH. B. SallamAfaf A. R. El-mariahE. DayalanE. GiglioD. T. WasanD. T. WasanA. BalernaN. V. PavelJ. SowaEric W. KalerQizhi HeE. Tronel-peyrozJ. JoshiR. L. BlokhraG. N. CaseG. M. MalikTatsuo AraiTatsuo AraiK. S. RaoC. B. DouglasF. M. MengerD. F. NicoliA. ShiraziE. Peris-cardellsM. G. SceatsJiri BarekAngelos MalliarisV. TalanquerN. M. WilsonG. CaminatiG. CaminatiT. N. NagarF. OrtegaC. F. BaesJ. M. VendelMichael L. KleinV. SrinivasA. M. BellocqG. G. WarrS. PuvvadaC. ChachatyPeiqiang WuKenji MoriCh. Durga PrasadH. Mohindra ChawlaL. M. TrejoJiri ZimaTatsumi TokumaruTatsumi TokumaruE. A. MoussaR. A. AliK. N. PanchalC. S. SodhiE. NavaD. SchiederTh. F. TadrosE. Bernieri

subject

Cloud pointViscosityPulmonary surfactantChemistryCritical micelle concentrationAssociation (object-oriented programming)Micellar solutionsIonic bondingThermodynamicsMicelle

description

A theoretical model describing the association of ionic surfactants into rod-shaped micelles is combined with an approximate formula for the viscosity increase induced by rod-shaped aggregates. It is shown that most of the thermodynamic parameters of the association model can be obtained from viscosity measurements. The approach is applied to micellar solutions of hexadecylpyridinium salts. The pronounced effect of counter-ion concentration on the growth of rod-shaped micelles can be attributed to a slightly higher degree of counter-ion association in the cylindrical part than in the end portions. An attempt is made to explain the finding that the degree of counter-ion association is virtually independent of counter-ion concentration.

https://doi.org/10.1007/978-1-4615-3836-3_42