6533b853fe1ef96bd12ac998

RESEARCH PRODUCT

ChemInform Abstract: Palladium-Catalyzed Skeletal Rearrangement of Spirotricyclic Olefins: A Facile One-Pot Strategy for the Synthesis of a Novel Motif with Cyclopentene Fused to Benzofuran and Pyrazolidine.

Kokkuvayil Vasu RadhakrishnanE. JijyPetri M. PihkoPraveen PrakashPreethalayam PreethanujSarngadharan Sarath Chand

subject

Pyrazolidinechemistry.chemical_compoundStereospecificityChemistryCyclopentenechemistry.chemical_elementGeneral MedicineBenzofuranRing (chemistry)Combinatorial chemistryCatalysisPalladiumCyclopropane

description

The first utilization of acyclic cyclopropane bearing spirocyclic olefines for the generation of stereospecific complex fused ring systems with an achiral catalyst is reported.

https://doi.org/10.1002/chin.201352123