6533b853fe1ef96bd12ac9d1

RESEARCH PRODUCT

Chemistry of lanthanide–metal carbonyl systems: the ytterbium–chromium carbonyls interaction

M. AddamoM.d. GrilloneMaurizio Volpe

subject

YtterbiumLanthanidechemistry.chemical_classificationMechanical EngineeringAcetylacetoneInorganic chemistryMetals and Alloyschemistry.chemical_elementInfrared spectroscopyMetal carbonylChemical synthesisCoordination complexchemistry.chemical_compoundChromiumchemistryMechanics of MaterialsMaterials Chemistry

description

Abstract The interaction of the chromium carbonyl hydrides HCr2(CO)10− or HCr(CO)5− with Yb(acac)3·3H2O has been investigated, and the experimental conditions leading to the isolation of ytterbium–chromium carbonyl complex species are reported. Formulation of the coordination compounds produced by such interactions has been proposed on the basis of analytical data and IR spectroscopy.

https://doi.org/10.1016/s0925-8388(01)00986-0