6533b853fe1ef96bd12ace33
RESEARCH PRODUCT
Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation.
André L. AmorimMatti HaukkaBernardo De SouzaRosely A. PeraltaFernando R. XavierEbbe NordlanderVitor C. WeissMayana B. BregaldaTiago P. CamargoGiliandro Fariassubject
Inorganic ChemistryCo deliveryChemistryIrradiationPhysical and Theoretical ChemistryCo releaseLuminescencePhotochemistryBlue lightdescription
The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-09-09 | Inorganic chemistry |