6533b854fe1ef96bd12ae0ce

RESEARCH PRODUCT

Crystal structure and Hirshfeld surface analysis of (E)-4-chloro-N-{2-[2-(4-nitro­benzyl­idene)hydrazin-1-yl]-2-oxoeth­yl}benzene­sulfonamide N,N-di­methyl­formamide monosolvate

H. PurandaraSabine ForoB. Thimme Gowda

subject

Formamidecrystal structureHydrazoneCrystal structureDihedral angle010402 general chemistry010403 inorganic & nuclear chemistryRing (chemistry)01 natural sciencesMedicinal chemistryResearch Communicationslcsh:Chemistrychemistry.chemical_compoundhydrazoneHirshfeld surface analysisGeneral Materials Sciencechemistry.chemical_classificationSchiff baseHydrogen bondinter­molecular hydrogen bondsAromaticityGeneral ChemistryCondensed Matter Physics0104 chemical sciencesintermolecular hydrogen bondslcsh:QD1-999chemistryinversion dimers

description

Reaction of N-(4-chloro­benzene­sulfon­yl)glycinyl hydrazide with 4-nitro­benzaldehyde gives the N,N-di­methyl­formamide monosolvated N-acyl­hydrazone derivative, (E)-N-{2-[2-(4-nitro­benzyl­idene)- hydrazine-1-yl]-2-oxoeth­yl}-4-χhloro­benzene­sulfonamide. Rings of (10) and (11) graph-set motifs are formed in the crystal structure by N—H⋯O and C—H⋯O hydrogen bonds. The two-dimensional fingerprint (FP) plots for significant inter­molecular inter­actions indicate that the greatest contribution is from the O⋯H/H⋯O contacts (31.3%), corresponding to N⋯H⋯O/C⋯H⋯O inter­actions.

yearjournalcountryeditionlanguage
2018-03-01Acta Crystallographica Section E: Crystallographic Communications
10.1107/s205698901800292xhttp://europepmc.org/articles/PMC5947811