Influence of Cation Size on the Fluorescent Properties of Bis-coronand Biphenyl-derived Complexes

6533b854fe1ef96bd12ae8c6

RESEARCH PRODUCT

Influence of Cation Size on the Fluorescent Properties of Bis-coronand Biphenyl-derived Complexes

Salvador Gil Vicente Añó Sanz Joaquin Sanchis Ana M. Costero

subject

Biphenyl Crystallography chemistry.chemical_compound Chemistry Analytical chemistry General Chemistry Fluorescence Stoichiometry

description

A new bis-coronand derived from biphenyl has been prepared and its complexing and sensing properties for alkaline, alkaline-earth and transition cations have been studied. Open and clamp complexes are formed depending on the cation size and complex stoichiometry. Both types of geometries can be distinguished due to their different fluorescent behaviour. Zn2+ gives rise to 1:1 and 1:2 complexes with a similar geometry.

year	journal	country	edition	language
2007-04-01	Supramolecular Chemistry

https://doi.org/10.1080/10610270600915300

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