6533b854fe1ef96bd12ae9ab

RESEARCH PRODUCT

A bis-exTTF macrocyclic receptor that associates C60 with micromolar affinity

María GallegoEmilio M. PérezRafael ViruelaHelena IslaNazario MartínEnrique Ortí

subject

chemistry.chemical_compoundColloid and Surface ChemistryStereochemistryChemistryChlorobenzeneGeneral ChemistryReceptorBiochemistryBinding constantCatalysisOrders of magnitude (mass)

description

An exTTF-based macrocyclic receptor that associates C(60) with a binding constant10(6) M(-1) in chlorobenzene at room temperature is described. This represents an improvement of 3 orders of magnitude with respect to the previous examples of exTTF-based receptors and one of the highest binding constants toward C(60) reported to date.

10.1021/ja910107mhttp://hdl.handle.net/20.500.12614/684