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RESEARCH PRODUCT

ChemInform Abstract: Rate of Photon Absorption and Turnover Number: Two Parameters for the Comparison of Heterogeneous Photocatalytic Systems in a Quantitative Way

Vincenzo AugugliaroLeonardo PalmisanoMario Schiavello

subject

AnatasePhotonChemistryAnalytical chemistryPhotocatalysisQuantum yieldGeneral MedicineCrystallitePhotodegradationAbsorption (electromagnetic radiation)Turnover number

description

Abstract In order to correctly compare the performance of different photocatalytic systems using polycrystalline semiconductor oxides, two parameters are proposed: the rate of photon absorption (rpa) and the turnover number (tn). From these quantities the quantum yield (qy), which indicates the efficiency of the absorbed photons for promoting a reaction event, can be determined. The phenol photodegradation reaction, carried out in aqueous dispersions of polycrystalline TiO2 (anatase) of different preparation methods and sources, has been used as “test reaction” in order to determine the tn, rpa and qy values.

https://doi.org/10.1002/chin.199338337