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RESEARCH PRODUCT

Recent advances in electrochemical meso- and β-functionalization of porphyrins and electrografting of diazonium porphyrins

Asmae BousfihaAbdou K. D. DimeCharles H. Devillers

subject

Anodic nucleophilic substitution02 engineering and technology010402 general chemistryPhotochemistryElectrochemistry01 natural sciencesDiazonium-porphyrin electrograftingAnalytical ChemistryPorphyrinchemistry.chemical_compoundOrganic electrosynthesis[CHIM.ANAL]Chemical Sciences/Analytical chemistryElectrochemistry[CHIM.COOR]Chemical Sciences/Coordination chemistry[CHIM.ORGA]Chemical Sciences/Organic chemistryIntermolecular forceElectropolymerization[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnologyPorphyrin0104 chemical sciencesCoupling (electronics)chemistryIntramolecular forceSurface modification0210 nano-technology

description

Abstract Recent studies on electrochemical meso- and β-functionalization of porphyrins and electrografting of diazonium porphyrin are presented. First, the electrochemical oxidative C–C coupling between porphyrins will be presented, followed by the intermolecular and intramolecular meso- and β-substitutions of porphyrins. Then, the latest results on diazonium porphyrin electrografting will be reviewed.

10.1016/j.coelec.2020.07.004https://hal.archives-ouvertes.fr/hal-03419604